Entropy additivity from exponential decay of correlations: a coarse-grained operator approach (opens in new tab)

Thermodynamic extensivity is commonly introduced as a postulate -- the homogeneity of degree one in thermodynamic potentials. We provide a constructive derivation of this property from microscopic conditions on the pair potential, without assuming it. Working with the one- and two-particle reduced densities of the $N$-body canonical Gibbs state, we introduce a combined coarse-graining operator $\mathcal{C}$ on single-particle phase space $\mathc...