On the emergence of molecular tilt in a ferroelectric smectic liquid crystal with broken director-inversion symmetry (opens in new tab)

The origin of some mesophases of the ferroelectric nematic realm is not yet well understood. In this work we study the highly polar liquid crystal MIO, a close structural analogue of the prototypical ferroelectric nematogen DIO, which exhibits a ferroelectric smectic A to ferroelectric smectic C (SmAF-SmCF) phase transition. Calorimetric, dielectric and light-scattering experiments reveal that it is a second-order phase transition with mean-fiel...